Frambinone® (CAS N° 5471-51-2)​

Photo credits: ScenTree SAS

Fruity > Berries > Musky > Dry Woods

Frambinone®

Raspberry Ketone® ; 4-(4-hydroxyphenyl)butan-2-one ; 4-(3-oxobutyl)phenol ; Para-hydrobenzyl acetone ; 1-para-hydroxyphenyl-3-butanone ; 4-(4-hydroxyphenyl)-2-butanone ; 1-(4- hydroxyphenyl)-3-butanone ; Para-hydroxyphenylbutanone ; N112 ; N 112 ; Oxanone ; Oxyphenylon ; Rasketone ; Raspberry keytone ; Rastone ; Rheosmin

Frambinone® (CAS N° 5471-51-2)​

Photo credits: ScenTree SAS

Company Ingredient Name ID Naturality Purity Latin name Treated part Geographical origin Certifications Comments MOQ
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Frambinone - 30 Gr - - - - - - more -

Ingredient Name : Frambinone - 30 Gr

Certifications :

Information Générales

General Presentation

  • CAS N° : 5471-51-2

  • EINECS number : 226-806-4

  • FEMA number : 2588

  • Density : N/A

  • Optical rotation : Donnée indisponible

  • Allergens : This ingredient does not contain any allergen.

  • Refractive Index @20°C : Donnée indisponible

  • Volatility : Heart/Base

  • Price Range : €€

  • Appearance : White solid

  • FLAVIS number : 07.055

  • JECFA number : 728

Information on synthetic ingredients

  • Acid Value : Donnée indisponible

  • Boiling Point : 292°C

  • Detection Threshold : 0,1 ppm (0,00001%)

  • Molecular formula : C10H12O2

  • Log P : 0,94

  • Molecular Weight : 164,2 g/mol

  • Fusion Point : 83°C

  • Flash Point : 94°C

  • Vapor pressure : Donnée indisponible

Utilisation

Uses

Other comments :

Stability :

Stable in perfumes and diverse functional bases

Uses in perfumery :

Frambinone® brings a fruity evocation in all types of accords. Used in raspberry reconstitutions and other red fruit notes.

Year of discovery :

1918

Isomerism :

The meta and ortho positional isomers of Frambinone® are not used in perfumery. Styrallyl acetate, Eugenol and Benzyl Propionate are some of the constitutional isomers of Frambinone® that are used in perfumery. Their smell is however very different, as it is fruity-rhubarb, spicy or floral-white flowers.

Synthesis precursor :

Frambinone® is not a precursor to the synthesis of another compound of olfactory interest.

Natural availability :

Frambinone® is present in several fruits and is extractable in its natural state, but only synthetic Frambinone® is used in perfumery.

Synthesis route :

Frambinone® is synthesized in two steps. The first is a condensation between 4-hydroxybenzaldehyde and acetone, to obtain 4-hydroxybenzalacetone. A catalytic and selective hydrogenation of the double bond formed allows to obtain the final product, Frambinone®.

Utilisation

Regulations & IFRA

  • IFRA 51th : This ingredient is restricted by IFRA

  • Restriction type : RESTRICTION

  • Cause of restriction : DEPIGMENTATION

  • Amendment : 49

Quantitative limit on the use :
Cat.1 Cat.2 Cat.3 Cat.4
Cat.5
A B C D
Cat.6
0,68 % 1 % 0,27 % 1 %
1 % 0,14 % 0,27 % 0,045 %
0,82 %
Cat.5
A B C D
Cat.6
1 % 0,14 % 0,27 % 0,045 %
0,82 %
Cat.7
A B
Cat.8 Cat.9
Cat.10
A B
Cat.11
A B
Cat.12
0,41 % 0,41 %
0,045 % 1 %
1 % 1 %
0,045 % 0,045 %
78 %
Cat.10
A B
Cat.11
A B
Cat.12
1 % 1 %
0,045 % 0,045 %
78 %

Comments :

4-(4-Hydroxyphenyl)butan-2-one has been found in natural extracts but only at trace levels.

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